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Abstract

This paper presents a comprehensive optimization study of hydrogen production systems through alkaline water electrolysis powered by photovoltaic energy sources, with a specific focus on Central Asian applications. The research systematically investigates critical operating parameters including KOH electrolyte concentration (25-30 wt%), temperature effects (25-80°C), current density optimization (100-500 mA/cm²), and electrode material performance using cost-effective 316L stainless steel. Experimental results demonstrate that optimized systems achieve solar-to-hydrogen efficiency of 13-15%, with hydrogen production costs ranging from $2-8/kg depending on system scale. The study reveals that maximum performance occurs at 30 wt% KOH concentration, 60-80°C operating temperature, and 200-400 mA/cm² current density. Long-term stability testing over 1000 hours confirms electrode degradation rates below 0.01 mm/year and performance degradation under 2%, validating projected operational lifetimes exceeding 20 years. For high solar irradiation regions like Uzbekistan (>2000 kWh/m²/year), the analysis indicates potential hydrogen production cost reductions of 20-30% compared to temperate climates. The integration of maximum power point tracking control improves overall energy utilization by 12-15% relative to direct coupling configurations. These findings provide practical guidelines for implementing economically viable green hydrogen production systems in solar-rich developing regions.

First Page

28

Last Page

37

References

  1. International Energy Agency. (2023). Global Hydrogen Review 2023. IEA Publications, Paris, 156 p.
  2. Smith, J.A., Brown, K.L. (2022). Fundamentals of Hydrogen Energy Systems. Academic Press, London, 324 p.
  3. Zhang, W., Li, M. (2023). Energy density comparison of various fuels. International Journal of Hydrogen Energy, 48(15), 5842-5861.
  4. European Commission. (2024). EU Hydrogen Strategy Implementation Report. EC Publications, Brussels, 289 p.
  5. Tanaka, H., Yamamoto, S. (2023). Japanʼs hydrogen society roadmap. Energy Policy, 172, 89-102.
  6. Marfin, E.A. (2023). Prospects for hydrogen energy development in Central Asia. Energy Policy Review, 3, 84-91.
  7. Nicholson, W., Carlisle, A. (1800). Account of the new electrical or galvanic apparatus. Journal of Natural Philosophy, Chemistry and the Arts, 4, 179-187.
  8. Buttler, A., Spliethoff, H. (2018). Current status of water electrolysis for energy storage. Renewable and Sustainable Energy Reviews, 82, 2440-2454.
  9. Schmidt, O., et al. (2017). Future cost and performance of water electrolysis. International Journal of Hydrogen Energy, 42, 30470-30492.
  10. Zhang, K., et al. (2023). Recent advances in alkaline water electrolysis. Chemical Engineering Journal, 451, 138398.
  11. Kumar, S., Singh, R. (2023). Optimization of PV-electrolyzer direct coupling systems. Solar Energy, 231, 115-128.
  12. Yang, Z., Liu, H. (2023). Power management in PV-electrolyzer systems. IEEE Transactions on Energy Conversion, 38(1), 234-248.
  13. Martinez, J., et al. (2023). Predictive control strategies for renewable hydrogen production. Applied Energy, 332, 120487.
  14. Brown, T.J., Wilson, K. (2023). Corrosion resistance of stainless steels in alkaline media. Corrosion Science, 210, 110812.
  15. Chen, L., Wang, X. (2023). Nanostructured catalysts for enhanced water splitting. ACS Catalysis, 13(4), 2156-2171.
  16. Thompson, R., Adams, K. (2023). Economic analysis of electrode materials for industrial electrolysis. Energy Economics, 117, 106432.
  17. IRENA. (2023). Green Hydrogen Cost Reduction: Scaling up Electrolysers. International Renewable Energy Agency, Abu Dhabi, 124 p.
  18. Yılmaz, C., Kanoglu, M. (2022). Thermodynamic evaluation of geothermal energy powered hydrogen production. International Journal of Hydrogen Energy, 47(26), 13281-13293.
  19. Shiva Kumar, S., Himabindu, V. (2019). Hydrogen production by PEM water electrolysis. Materials Science for Energy Technologies, 2(3), 442-454.
  20. Mohammadi, A., Mehrpooya, M. (2018). A comprehensive review on coupling different types of electrolyzer to renewable energy sources. Energy, 158, 632-655.
  21. Zhao, Y., et al. (2023). Performance analysis of PV-powered alkaline electrolyzers for hydrogen production in desert regions. Energy Conversion and Management, 281, 116852.
  22. Bak, T., et al. (2002). Photo-electrochemical hydrogen generation from water using solar energy. International Journal of Hydrogen Energy, 27(10), 991-1022.
  23. Turner, J., et al. (2008). Renewable hydrogen production. International Journal of Energy Research, 32(5), 379-407.
  24. Kacprzak, A., Kobylecki, R. (2014). Hydrogen production by alkaline water electrolysis. Interdisciplinary Journal of Engineering Sciences, 2(1), 6-12.
  25. Ursúa, A., et al. (2012). Integration of commercial alkaline water electrolysers with renewable energies. International Journal of Hydrogen Energy, 37(23), 18067-18075.
  26. Atlam, O., Kolhe, M. (2011). Equivalent electrical model for a proton exchange membrane fuel cell. Energy Conversion and Management, 52(8-9), 2952-2957.
  27. Diéguez, P.M., et al. (2008). Thermal performance of a commercial alkaline water electrolyzer. International Journal of Hydrogen Energy, 33(24), 7338-7354.
  28. Atlam, O., Barbir, F. (2010). Control strategy for optimum coupling between photovoltaic panels and alkaline electrolysers. Journal of Power Sources, 195(10), 2951-2958.

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